Activating Windows from cmd usually takes two steps using slmgr.vbs tool:
Local Machine
Step 1: Change product key to valid one
slmgr /ipk XXX-YOUR-VALID-WIN-CODE-XXX
Step 2: Run online activation
slmgr /ato
If you prefer single-line command:
slmgr /ipk XXX-YOUR-VALID-WIN-CODE-XXX&&slmgr /ato
Process does take some time, so be patient.
Remote Machine
Same can be achieved on a remote machine, but success may vary depending on the permission/network settings:
slmgr 192.168.100.100 admin-user password /ipk XXX-YOUR-VALID-WIN-CODE-XXX slmgr /ato
Your (usually volume licensed) PC should now be activated.